Most heirlooms only work in a limited level range in their default form and must be upgraded to work at higher levels. That costs gold, and you’ll need around 30,000 gold to outfit yourself with a fully upgraded set (counting only those that give you bonus experience). You may need to spend some time on a boosted character to acquire the gold you need to outfit another character with heirlooms, but it’s well worth the effort.
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90-91 i collected treasures that gave resources and then dumped them all in xp potions and began to clean up shadowmoon valley while also doing bonus objectives, after shadowmoon i went to gorgrond and did the same thing and then to talador for a bit before I was 96 and went to quest in arak until I was 98 when I picked up my artifact and went back for the last few levels. Overall 90-100 took like 4 hours.
I've used WoW-Pro for years and in WoD, Legion and now BfA it's been awesome for just going on auto-pilot and working your way through a zone. It has 3 levels of depth you can set, so you can set it to just do 1) the main story, main points of interest and rare mobs and treasure that aren't far off the beaten path; 2) every quest with a more thorough dive into the side stuff; 3) absolutely everything.