No he's just not paying attention. The wanted quests are built into both the leveling guides and the "Zandalar Forever" achievement guide. They aren't in the rep guide because they are not repeatable and by the time you hit max level they should be done. You'll also notice the rep guide doesn't contain every single possible completable quest that rewards rep. It is designed to focus on repeatable objectives, world quests, large quest lines, and missions.
2. Your DH needs supplies on a regular basis. They can only carry so much food, clean drink, medical potions and whatever else they want/need at a time. It's pretty realistic that they would need to visit a market every so often, and large faction markets will have the most variety and types of items to choose from. (My DH has been a recluse in the wild for some time, and she is stinky, dirty and has eaten some questionable stuff. This isn't really ideal and a Dalaran doughnut would be pretty flippin nice.)